Picropharmacolite, Ca4Mg(AsO3OH)2(AsO4)2·11H2O, is a rare arsenate mineral. It was named in 1819 from the Greek for bitter, in allusion to its magnesium content, and its chemical similarity to pharmacolite , Ca4Mg(AsO3OH)2(AsO4)2·4H2O, has the same composition as picropharmacolite, except that it has only four water molecules per formula unit, instead of eleven. It may be formed by the dehydration of picropharmacolite.